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Cross-linked polyethylene (PEX) pipes used in hot water supply are required for high mechanical strength and high creep resistance at high temperature. PEXa pipes which are made by peroxide cross-linking have better performance, such as creep resistance and thermal shock resistance than the pipes made by other cross-kinking method. Finished PEXa pipe can be coated with EVOH oxygen barrier and other protection layer, by another separate extrusion line, to get a 3 layer PEXa EVOH oxygen barrier pipe or 5 layer PEXa EVOH oxygen barrier pipes. The three layer PEXa oxygen barrier pipe strucrues are: PEXa pipe, adhesive layer, and outer EVOH oxygen barrier layer. However the five PEXa oxygen barrier pipe structures are: inner PEXa pipe, adhesive layer, Middle EVOH oxygen barrier pipe, Adhesive layer, and outer PE protection layer.